Search results for "chemistry [Peptide Fragments]"
showing 10 items of 2849 documents
Crystal field and magnetism with Wannier functions: Rare-earth doped aluminum garnets
2015
Using the recently developed method we calculate the crystal field parameters in yttrium and lutetium aluminum garnets doped with seven trivalent Kramers rare-earth ions. We then insert calculated parameters into the atomic-like Hamiltonian taking into account the electron-electron, spin-orbit and Zeeman interactions and determine the multiplet splitting by the crystal field as well as magnetic $\hat{g}$ tensors. We compare calculated results with available experimental data.
The crater lake of Ilamatepec (Santa Ana) volcano, El Salvador: insights into lake gas composition and implications for monitoring
2019
We here present the first chemical characterization of the volcanic gas plume issuing from the Santa Ana crater lake, a hyper-acidic crater lake (pH of − 0.2 to 2.5) in north-western El Salvador. Our results, obtained during regular surveys in 2017 and 2018 using a Multi-GAS instrument, demonstrate a hydrous gas composition (H2O/SO2 ratios from 32 to 205) and SO2 as the main sulfur species (H2S/SO2 = 0.03–0.1). We also find that gas composition evolved during our investigated period, with the CO2/SO2 ratio decreasing by one order of magnitude from March 2017 (37.2 ± 9.7) to November 2018 (< 3). This compositional evolution toward more magmatic (SO2-rich) compositions is interpreted in the c…
KOSMOS 2017 Peru Side Experiment: nutrients, phytoplankton abundances, enzyme rates, photophysiology
2022
This data was collected during an short-term incubation experiment in March 2017 that investigated the response of a surface plankton community to upwelling. This experiment was carried in the framework of the SFB754-funded KOSMOS mesocosm study that took place in La Punta, Callao, Peru between February-April 2017. A total of six different treatments were used to disentangle chemical and biological characteristics of deep water that influence surface plankton blooms: 2 different deep water sources with different nutrient concentrations; 3 treatments to distinguish the effects of inorganic nutrients, organic nutrients and deep water microbial populations. Measured variables include inorganic…
The SO2F2 quasi-spherical top: Correspondence between tensorial and Watson's formalisms
2006
Abstract The SO2F2 quasi-spherical top molecule with C2v symmetry is considered as a distorted spherical top deriving from the SO 4 2 − tetrahedral ion. We present here a detailed correspondence between the tensorial formalism using the Td⊃C2v reorientation and the usual Hamiltonian of Watson. We have also performed ab initio calculations in order to determine the centrifugal distorsion constants in the vibrational ground state.
Investigation of a Gravel-Bed River’s Pattern Changes: Insights from Satellite Images
2021
Changes in river pattern have been documented in the literature. The recognition of islands and vegetated patches, which is indicative of the evolution processes, requires simultaneous information at different points and at different times and field studies are still difficult and scarce. The present work, focusing the attention on a gravel-bed river, explores the possibility to conduct a first-step pattern changes analysis by identifying the evolution of the morphological features and taking information of islands and vegetated patches from satellite images easily available from Google Earth. The study is conducted by combining the information taken from both the satellite images and the f…
A method for measuring wetting and swelling of bentonite using X-ray imaging
2022
A non-invasive method based on X-ray imaging for measuring deformation and water transport in wetting and swelling bentonite samples is introduced. Sequential X-ray images taken of the samples were used to calculate the attenuation coefficient and deformation. These results, together with careful calibration, allowed finding the dry density and water content distributions and their temporal evolution in the wetting and swelling samples. A specific correction technique, based on regularly taking reference X-ray images of aluminum plates of varying thickness, was developed and used to take into account X-ray beam instabilities and thus to improve the accuracy of density analysis. Large deform…
Psychrophiles: A source of cold-adapted enzymes for energy efficient biotechnological industrial processes
2021
Biocatalysts are the backbone of bioprocessing industries that are going through a phase of transition with reference to the requirement of extraordinary enzymes for various biochemical processes. This transition is well reported and documented by various researchers through elucidation of different features and applications of mesophilic and thermophilic enzymes. However, there is little information available about psychrophilic enzymes and their involvement in industrial processes. Therefore, understanding the features and functions of psychrophilic enzymes could suggest some of their novel applications in various industries such as food, agriculture, chemicals, pharmaceuticals, and waste…
Stress sensitivity of stylolite morphology
2009
International audience; Stylolites are rough surfaces that form by localized stress-induced dissolution. Using a set of limestone rock samples collected at different depths from a vertical section in Cirque de Navacelles (France), we study the influence of the lithostatic stress on the stylolites morphology on the basis of a recent morphogenesis model. We measured the roughness of a series of bedding-parallel stylolites and show that their morphology exhibits a scaling invariance with two self-affine scaling regimes separated by a crossover-length (L) at the millimeter scale consistent with previous studies. The importance of the present contribution is to estimate the stylolite formation s…
Zinc Adsorption by Activated Carbon Prepared from Lignocellulosic Waste Biomass
2019
Sawdust was used as a precursor for the production of biomass-based activated carbon. Carbonization and activation are single-stage processes, and steam was used as a physical activation agent at 800 °
On the use of composite indicators for mobile communications network management in smart sustainable cities
2020
Beyond 5G networks will be fundamental towards enabling sustainable mobile communication networks. One of the most challenging scenarios will be met in ultra-dense networks that are deployed in densely populated areas. In this particular case, mobile network operators should benefit from new assessment metrics and data science tools to ensure an effective management of their networks. In fact, incorporating architectures allowing a cognitive network management framework could simplify processes and enhance the network&rsquo